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Please use this identifier to cite or link to this item: http://hdl.handle.net/1959.14/289869
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- Title
- Assimilation of sediments embedded in the oceanic arc crust : myth or reality?
- Related
- Earth and planetary science letters, Vol. 395, (2014), p.51-60
- DOI
- 10.1016/j.epsl.2014.03.038
- Publisher
- Elsevier
- Date
- 2014
- Author/Creator
- Bezard, Rachel
- Author/Creator
- Davidson, Jon P
- Author/Creator
- Turner, Simon
- Author/Creator
- Macpherson, Colin G
- Author/Creator
- Lindsay, Jan M
- Author/Creator
- Boyce, Adrian J
- Description
- Arc magmas are commonly assumed to form by melting of sub-arc mantle that has been variably enriched by a component from the subducted slab. Although most magmas that reach the surface are not primitive, the impact of assimilation of the arc crust is often ignored with the consequence that trace element and isotopic compositions are commonly attributed only to varying contributions from different components present in the mantle. This jeopardises the integrity of mass balance recycling calculations. Here we use Sr and O isotope data in minerals from a suite of volcanic rocks from St Lucia, Lesser Antilles arc, to show that assimilation of oceanic arc basement can be significant. Analysis of ⁸⁷Sr/⁸⁶Sr in single plagioclase phenocrysts from four Soufrière Volcanic Complex (SVC; St Lucia) hand samples with similar composition (⁸⁷Sr/⁸⁶Sr=0.7089-0.7091) reveals crystal isotopic heterogeneity among hand samples ranging from 0.7083 to 0.7094 with up to 0.0008 difference within a single hand sample. δ¹⁸O measurements in the SVC crystals show extreme variation beyond the mantle range with +7.5 to +11.1‰ for plagioclase (n = 19), +10.6 to +11.8‰ for quartz (n = 10), +9.4 to +9.8‰ for amphibole (n = 2) and +9 to +9.5‰ for pyroxene (n = 3) while older lavas (Pre-Soufriere Volcanic Complex), with less radiogenic whole rock Sr composition (⁸⁷Sr/⁸⁶Sr=0.7041-0.7062) display values closer to mantle range: +6.4 to +7.9‰ for plagioclase (n = 4) and +6 to +6.8‰ for pyroxene (n = 5). We argue that the ⁸⁷Sr/86Sr isotope disequilibrium and extreme δ¹⁸O values provide compelling evidence for assimilation of material located within the arc crust. Positive correlations between mineral δ¹⁸O and whole rock ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd and ²⁰⁶'²⁰⁷'²⁰⁸Pb/²⁰⁴Pb shows that assimilation seems to be responsible not only for the isotopic heterogeneity observed in St Lucia but also in the whole Lesser Antilles since St Lucia encompasses almost the whole-arc range of isotopic compositions. This highlights the need for detailed mineral-scale investigation of oceanic arc suites to quantify assimilation that could otherwise lead to misinterpretation of source composition and subduction processes.
- Description
- 10 page(s)
- Subject Keyword
- Assimilation
- Subject Keyword
- Lesser Antilles
- Subject Keyword
- Mineral Sr isotopes
- Subject Keyword
- Mineral δ¹⁸O
- Subject Keyword
- Oceanic arcs
- Resource Type
- journal article
- Organisation
- Macquarie University. Department of Earth and Planetary Sciences
- Organisation
- Macquarie University. Centre of Excellence for Core to Crust Fluid Systems
- Organisation
- Macquarie University. National Key Centre for Geochemical Evolution and Metallogeny of Continents (GEMOC)
- Identifier
- http://hdl.handle.net/1959.14/289869
- Identifier
- mq:31137
- Identifier
- ISSN:0012-821X
- Identifier
- mq-rm-2013002629
- Identifier
- mq_res-ext-2-s2.0-84897551068
- Language
- eng
- Reviewed
